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Biodiesel production is the process of making biodiesel. Biodiesel is a liquid fuel source largely compatible with petroleum based diesel fuel. It is synthesized by replacing glycerol with a short chain alcohol such as methanol or ethanol in a step known as transesterification. more...

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Transesterification chemistry

A reaction scheme is as follows:

Animal and plant fats and oils are typically made of triglycerides which are esters of free fatty acids with the trihydric alcohol, glycerol. In the transesterification, the alcohol is deprotonated with a base to make it a stronger nucleophile. Commonly, ethanol or methanol is used. As can be seen, the reaction has no other inputs than the triglyceride and the alcohol.

Normally, this reaction will proceed either exceedingly slowly or not at all. Heat, as well as an acid or base are used to help the reaction proceed more quickly. It is important to note that the acid or base are not consumed by the transesterification reaction, thus they are not reactants but catalysts.

Almost all biodiesel is produced using the base-catalyzed technique as it is the most economical process requiring only low temperatures and pressures and producing over 98% conversion yield (provided the starting oil is low in moisture and free fatty acids). For this reason only this process will be described below.

The following steps can be performed in a small, home-based biodiesel processor, or in large industrial facilities. The chemistry is similar in either case.

Steps in the process

The major steps required to synthesize biodiesel are as follows:

Purification

If waste vegetable oil is used, it is filtered to remove dirt, charred food, and other non-oil material often found.

Water is removed because its presence causes the triglycerides to hydrolyze to give salts of the fatty acids instead of undergoing transesterification to give biodiesel.

At home, this is often accomplished by heating the filtered oil to approximately 120°C. At this point, dissolved or suspended water will boil off. When the water boils, it spatters (chemists refer to it as "bumping"). To prevent injury, this operation should be done in a sufficiently large container (at most two thirds full) which is closed but not sealed.

In the laboratory, the crude oil may be stirred with a drying agent such as magnesium sulfate to remove the water in the form of water of crystallization. The drying agent can be separated by decanting or by filtration. However, the viscosity of the oil may not allow the drying agent to mix thoroughly.

Neutralization of free fatty acids

A sample of the cleaned oil is titrated against a standard solution of base in order to determine the concentration of free fatty acids (RCOOH) present in the waste vegetable oil sample. The quantity (in moles) of base required to neutralize the acid is then calculated.

Read more at Wikipedia.org